Fehling's Test
A qualitative test distinguishing aliphatic aldehydes from ketones and aromatic aldehydes.
1. Setup Experiment
Select Unknown Compound
2. Observation
Physical State
Clear Liquid
Status: Standby.
Select an organic compound and click "Add Fehling's Reagent". Fehling's A (CuSO4) and Fehling's B (Rochelle salt) are mixed to form a deep blue complex.
Select an organic compound and click "Add Fehling's Reagent". Fehling's A (CuSO4) and Fehling's B (Rochelle salt) are mixed to form a deep blue complex.
3. Redox Chemistry
Aliphatic Aldehydes are easily oxidized to carboxylic acids.
Cu2+ ions (deep blue) are reduced to Cu+, forming insoluble Cu2O (brick-red).
R-CHO + 2Cu2+ + 5OH- →
R-COO- + Cu2O↓ + 3H2O
Ketones & Aromatic Aldehydes generally do not react.
Cu2+ ions (deep blue) are reduced to Cu+, forming insoluble Cu2O (brick-red).
R-CHO + 2Cu2+ + 5OH- →
R-COO- + Cu2O↓ + 3H2O
Ketones & Aromatic Aldehydes generally do not react.
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