Formality & Strength of Solution
Specific Concentration Terms | Basic Concepts of Chemistry
1. Formality ($F$)
Formality is very similar to Molarity, but it is specifically used for Ionic Compounds (like $NaCl$, $KNO_3$) which exist as formula units rather than discrete molecules.
Example: For NaCl, we use Formula Mass (58.5 g) instead of "Molecular Mass". Numerically, $F \approx M$ for strong electrolytes, but $F$ is theoretically more correct for ionic solids.
Temperature Effect: Depends on Volume ($V$), so Formality changes with temperature.
2. Strength of Solution ($S$)
This is the most direct way of expressing concentration in quantitative analysis (titrations).
Unit: $g/L$ or $g \cdot dm^{-3}$.
3. Important Relations
A. Strength vs Molarity ($M$)
$$ S = \text{Molarity} \times \text{Molar Mass} $$ $$ S (g/L) = M (mol/L) \times M_{wt} (g/mol) $$B. Strength vs Normality ($N$)
$$ S = \text{Normality} \times \text{Equivalent Mass} $$ $$ S (g/L) = N (eq/L) \times E_{wt} (g/eq) $$C. Formality vs Molarity
For molecular compounds (e.g., Glucose), $F = M$.
For ionic compounds, Formality uses observed Formula Mass, whereas Molarity often implies the theoretical molecular mass.
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Very nicely explained! Great work sir
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