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Group 18 Elements: Noble Gases, Configuration & Occurrence

Group 18 Elements: Noble Gases, Configuration & Occurrence | chemca
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Inorganic Chemistry • Group 18

Group 18 Elements: The Noble Gases

Complete Octets, High Stability, and Atmospheric Occurrence.

By chemca Team • Updated Sep 2026

At the extreme right of the periodic table lies Group 18. Unlike the violently reactive Halogens or Alkali metals, the elements of this group are characterized by their extreme chemical unreactivity. They exist as colorless, odorless, monoatomic gases at room temperature.

1. Meet the Noble Gases

Group 18 consists of Helium ($He$), Neon ($Ne$), Argon ($Ar$), Krypton ($Kr$), Xenon ($Xe$), Radon ($Rn$), and the synthetically produced super-heavy element Oganesson ($Og$).

Historically, they were called "Inert Gases" because chemists believed they could not form any compounds. However, in 1962, Neil Bartlett synthesized the first Xenon compound. Since they do react under specific, extreme conditions, they are now more accurately termed "Noble Gases" (similar to noble metals like Gold and Platinum, which react reluctantly).

Group 18: Monoatomic Gases & Closed Shells He Helium Ne Neon Ar Argon Kr Krypton Xe Xenon Rn Radon Og Oganesson All are Monoatomic Gases Radioactive Valence Shell: ns² np⁶ (Exception: Helium is 1s²) ns np Completely Filled Octet (Stable Shell) Results in extremely high Ionization Enthalpy and large positive Electron Gain Enthalpy

Figure 1: All elements in Group 18 are monoatomic gases at room temperature due to weak interatomic forces.

2. Electronic Configuration & Stability

All noble gases have general electronic configuration $ns^2 np^6$, except helium which has $1s^2$.

Because their outermost shell is completely filled (a stable octet/duplet), they have no tendency to lose, gain, or share electrons. This directly explains two of their most important properties:

Ionization Enthalpy They exhibit the highest ionization enthalpy in their respective periods. (However, it decreases down the group as atomic size increases).
Electron Gain Enthalpy Since they have stable configurations, they have no tendency to accept electrons. Thus, they have large positive values of electron gain enthalpy.

3. Occurrence in Nature

Where do we find elements that refuse to react with anything? Mostly floating freely in the atmosphere, or trapped underground.

A. The Atmosphere

All noble gases (except Radon and Oganesson) occur in the Earth's atmosphere.

  • Their total atmospheric abundance in dry air is ~1% by volume.
  • Argon ($Ar$) is the major constituent of this 1%.

B. Helium Sources

The main commercial source of Helium is natural gas. Helium is also found trapped in minerals of radioactive origin, such as pitchblende, monazite, and cleveite (due to alpha decay of uranium and thorium).

C. Radioactive Decay (Radon)

Radon ($Rn$) is obtained as a decay product of Radium-226.

$_{88}^{226}\text{Ra} \rightarrow _{86}^{222}\text{Rn} + _{2}^{4}\text{He}$

Oganesson ($Og$) is synthetically produced by colliding Californium ($Cf$) with Calcium ($Ca$) ions. It is highly radioactive with a half-life of less than a millisecond.

Physical Properties Note: Because noble gases are monoatomic, the only intermolecular forces acting between them are weak dispersion forces (London forces). This is why they have extremely low melting and boiling points. Helium has the lowest boiling point (4.2 K) of any known substance!

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